dc.contributor.author | Cetinkaya, Sevil | |
dc.contributor.author | Yasar, Emine | |
dc.date.accessioned | 2020-06-25T18:07:06Z | |
dc.date.available | 2020-06-25T18:07:06Z | |
dc.date.issued | 2013 | |
dc.identifier.citation | closedAccess | en_US |
dc.identifier.issn | 0926-860X | |
dc.identifier.uri | https://doi.org/10.1016/j.apcata.2013.05.030 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12587/5474 | |
dc.description | WOS: 000323805300017 | en_US |
dc.description.abstract | Modern well-defined ruthenium alkylidene complexes became preferred catalysts for a great variety of metathesis reactions. In this study, an air-stable new ruthenium alkylidene catalyst bearing 3-methoxypyridine has been prepared in one pot at high yields using commercially available [(PCy3)(2)Cl2Ru=CHPh] catalyst. Ruthenium based complex, (PCy3)(3-MeOPy)(2)(Cl)(2)Ru=CHPh, was characterized by a H-1 NMR doublet at 20.00 (J=11.9 Hz) for the Ru=CH proton. The catalyst was tested in model ROMP reactions and found to be very effective for ring-opening metathesis polymerization (ROMP). The optimal conditions for the polymerization of exo-N-benzylnorbornene-5,6-dicarboximide using the newly synthesized catalytic system were determined. (C) 2013 Elsevier B.V. All rights reserved. | en_US |
dc.description.sponsorship | Kirikkale University Foundation (Turkey)Kirikkale University [2011-08] | en_US |
dc.description.sponsorship | Financial support from the Kirikkale University Foundation (Turkey), (Project No. 2011-08) is gratefully acknowledged. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Elsevier Science Bv | en_US |
dc.relation.isversionof | 10.1016/j.apcata.2013.05.030 | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Ruthenium catalyst | en_US |
dc.subject | ROMP | en_US |
dc.subject | Metathesis | en_US |
dc.subject | Polynorbornene dicarboximide | en_US |
dc.subject | Homogeneous catalyst | en_US |
dc.title | Synthesis and catalytic evaluation of a ruthenium alkylidene complex bearing methoxy-pyridine ligand | en_US |
dc.type | article | en_US |
dc.contributor.department | Kırıkkale Üniversitesi | en_US |
dc.identifier.volume | 464 | en_US |
dc.identifier.startpage | 136 | en_US |
dc.identifier.endpage | 141 | en_US |
dc.relation.journal | Applied Catalysis A-General | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |