dc.contributor.author | Aydin, H. M. | |
dc.contributor.author | Salimi, K. | |
dc.contributor.author | Yilmaz, M. | |
dc.contributor.author | Turk, M. | |
dc.contributor.author | Rzayev, Z. M. O. | |
dc.contributor.author | Piskin, E. | |
dc.date.accessioned | 2020-06-25T18:22:33Z | |
dc.date.available | 2020-06-25T18:22:33Z | |
dc.date.issued | 2016 | |
dc.identifier.citation | closedAccess | en_US |
dc.identifier.issn | 1932-6254 | |
dc.identifier.issn | 1932-7005 | |
dc.identifier.uri | https://doi.org/10.1002/term.1759 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12587/6794 | |
dc.description | Bayram, Cem/0000-0001-8717-4668; yilmaz, mehmet/0000-0003-2687-9167; yilmaz, mehmet/0000-0003-2687-9167 | en_US |
dc.description | WOS: 000368577300004 | en_US |
dc.description | PubMed: 23671061 | en_US |
dc.description.abstract | In this study, poly(glycerol-co-sebacate-co-epsilon-caprolactone) (PGSCL) elastomers were synthesized for the first time from the respective monomers. The structural analysis of PGSCL elastomers by nuclear magnetic resonance (H-1-NMR) and Fourier transform infrared spectroscopy (FTIR) revealed that the elastomers have a high number of hydrogen bonds and crosslinks. X-ray diffraction (XRD) and thermal analysis indicated an amorphous state. Differential scanning calorimetry (DSC) analysis showed that the elastomers has a glass transition temperature (T-g) of -36.96 degrees C. The Young's modulus and compression strength values were calculated as 46.08MPa and 3.192MPa, respectively. Calculations based on acid number and end groups analysis revealed a number average molecular weight of 148.15kDa. Even though the foaming studies conducted by using supercritical CO2 resulted in a porous structure; the obtained morphology tended to disappear after 48h, leaving small cracks on the surface. This phenomenon was interpreted as an indication of self-healing due to the high number of hydrogen bonds. The PGSCL elastomers synthesized in this study are flexible, robust to compression forces and have self-healing capacity. Thanks to good biocompatibility and poor cell-adhesion properties, the elastomers may find diverse applications where a postoperative adhesion barrier is required. Copyright (c) 2013 John Wiley & Sons, Ltd. | en_US |
dc.description.sponsorship | Turkish Academy of SciencesTurkish Academy of Sciences | en_US |
dc.description.sponsorship | H.M.A. would like to thank B.M.T. Calsis for donation of the monomers. E.P. was supported by the Turkish Academy of Sciences as a full member. The authors thank Mr T. Vural and Mr C. Bayram for SEM analysis and Mr T. Cirak for his help in drawing the figures. PHB electrospun scaffolds were kindly donated by Dr M. Demirbilek. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Wiley-Blackwell | en_US |
dc.relation.isversionof | 10.1002/term.1759 | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | elastomers | en_US |
dc.subject | glycerol | en_US |
dc.subject | sebacic acid | en_US |
dc.subject | epsilon-caprolactone | en_US |
dc.subject | self-healing | en_US |
dc.subject | supercritical CO2 | en_US |
dc.title | Synthesis and characterization of poly(glycerol-co-sebacate-co-epsilon-caprolactone) elastomers | en_US |
dc.type | article | en_US |
dc.contributor.department | Kırıkkale Üniversitesi | en_US |
dc.identifier.volume | 10 | en_US |
dc.identifier.issue | 1 | en_US |
dc.identifier.startpage | E14 | en_US |
dc.identifier.endpage | E22 | en_US |
dc.relation.journal | Journal Of Tissue Engineering And Regenerative Medicine | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |