Karaaslan, Emine OzgulToka, Yasemin2020-06-252020-06-252007Karaaslan, E. Ö., Toka, Y. (2007). Chemoenzymatic synthesis of 2-bromo-6-hydroxy-3-methoxy-2-cyclohexen-1-one. Turkish Journal of Chemistry, 31(2), 149 - 153.1300-0527https://hdl.handle.net/20.500.12587/4025A chemoenzymatic synthesis of 2-bromo-6-hydroxy-3-methoxy-2-cyclohexen-1-one starting from cyclohexane-1,3-dione is reported. Manganese (III) acetate-mediated acetoxylation followed by the enzyme-mediated hydrolysis of alpha'-acetoxy enone affords hydroxy-enone 5 and enone 4 with high enantiomeric excesses in good yields.eninfo:eu-repo/semantics/openAccesschemoenzymatic synthesiscyclic polyoxo cyclohexenonesmanganese (III) acetateacetoxylationArticle3121491532-s2.0-34247495951Q3WOS:000246883000005Q3