Yazar "Bulut, Adnan" için listeleme
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1,4-diferrocenylbutane-1,4-dione
Tombul, Mustafa; Bulut, Adnan; Guven, Kutalmis; Buyukgungor, Orhan (Blackwell Publishing, 2008)In the crystal structure of the title compound, [Fe-2(C5H5)(2)-(C14H12O2)], each carbonyl group is coplanar with the adjacent cyclopentadienyl ring, thus maximizing the pi-orbital overlap and electronic interactions between ... -
Alkyl Lewis Acid Catalyzed Syntheses of Dicarbonyl Ferrocenes
Tombul, Mustafa; Gemici, S.; Bulut, Adnan (Asian Journal Of Chemistry, 2010)A series of diferrocenoyl compounds; succinyl (1), glutaryl (2), adipoyl (3), suberoyl (4) and sebacoyl ferrocene (5) were synthesized from the reaction of ferrocene with EtAlCl(2). Compared to the conventional methods ... -
Application of FAM ligands in the metal-promoted catalytic enantioselective synthesis of organic compounds
Dogan, Oezdemir; Garner, Philip P.; Bulut, Adnan (Scientific Technical Research Council Turkey-Tubitak, 2009)Novel ferrocenyl substituted aziridinyl methanol (FAM) ligands were synthesized and successfully used in metal-promoted catalytic enantioselective azomethine ylide cycloadditions, diethylzinc additions to enones, alkynylzinc ... -
Asimetrik diferrosenil kiral türevlerin sentezi
Bulut, Adnan; Kırıkkale Üniversitesi, Rektörlük, Projeler (KırıkkaleKırıkkale Üniversitesi, 9999)… -
Aziridin bazlı yeni bir kiral ligand ile asimetrik henry tepkimesi
Aslan, Ayhan (Kırıkkale Üniversitesi, 2009)Bu tezde aldehit ve ß-ketoesterlere asimetrik nitrometan katılması (Henry reaksiyonu) çalışılmıştır. 4 adet kiral FAM (ferrosenil aziridinil metanol) diasteromerik stereoizomerleri sentezlenmiş ve kiral katalizör olarak ... -
Catalytic asymmetric nitroaldol (Henry) reaction with a zinc-Fam catalyst
Bulut, Adnan; Aslan, Ayhan; Dogan, Oezdemir (Amer Chemical Soc, 2008)Ferrocenyl-substituted aziridinylmethanol (Fam-1) was used as a catalyst with zinc for the asymmetric nitroaldol (Henry) reaction. This catalyst worked with a variety of aldehydes (aromatic, aliphatic, alpha,beta-unsaturated, ... -
Catalytic enantioselective addition of diethylzinc to aldehydes using aziridine based chiral ligands
Bulut, Adnan; Aslan, Ayhan; İzgü, Enver Cağrı; Doğan, Özdemir (Pergamon-Elsevier Science Ltd, 2007)The readily available ferrocenyl substituted aziridinylmethanol 1 (FAM-1) was used as a chiral catalyst in the diethylzinc addition reaction to aromatic and aliphatic aldehydes to give secondary alcohols in high yields and ... -
Chiral phosphine oxide aziridinyl phosphonate as a Lewis base catalyst for enantioselective allylsilane addition to aldehydes
Dogan, Ozdemir; Bulut, Adnan; Tecimer, M. Ali (Pergamon-Elsevier Science Ltd, 2015)A series of chiral Lewis bases, phosphine oxide ferrocenyl aziridinyl methanol 1-4, phosphinyl aziridinyl phosphonates 5 and 6, and phosphine oxide aziridinyl phosphonates 7 and 8 were screened for allylsilane additions ... -
Copper-catalyzed asymmetric conjugate addition of diethylzinc to substituted chalcones using a chiral phosphine ligand
Dogan, Ozdemir; Bulut, Adnan; Polat, Savas; Tecimer, M. Ali (Pergamon-Elsevier Science Ltd, 2011)A series of chiral phosphine PFAM and phosphine oxide POFAM ligands were studied for the copper-catalyzed asymmetric diethylzinc addition to enones. One of these ligands, PFAM2, was an efficient catalyst with a variety of ... -
Crystal structure of dimethylammonium bis(naphthalene-2,3-diolato) borate, C22H20BNO4
Tombul, Mustafa; Guven, Kutalmis; Bulut, Adnan; Svoboda, Ingrid; Fuess, Hartmut (Walter De Gruyter Gmbh, 2018)C22H20BNO4, monoclinic, C2/c (no. 15), a = 32.303(4) angstrom, b = 8.2703(6) angstrom, c = 7.3876(6) angstrom, beta = 92.889(8)degrees, V = 1971.1(3) angstrom(3), Z = 4, R-gt(F) = 0.0978, wR(ref)(F-2) = 0.2063, T = 298 K. -
Efficient synthesis of ferrocenylenones by Friedel-Crafts acylation with EtAlCl2-Me3Al
Doğan, Özdemir; Şenol, Volkan; Zeytinci, Serhat; Koyuncu, Hasan; Bulut, Adnan (Elsevier Science Sa, 2005)Efficient synthesis of ferrocenyl en ones using a Friedel-Crafts acylation reaction is described. Acryloyl, methacryloyl, crotonoyl, cinnamoyl, and beta-methylcrotonoyl chlorides react with ferrocene in the presence of a ... -
Ferrosen Sübstitüe Aziridine Bileşiklerinin Sentezi
Bulut, Adnan; Doğan, Özdemir; Koyuncu, Hasan; Kırıkkale Üniversitesi, Rektörlük, Projeler (KırıkkaleKırıkkale Üniversitesi, 2003)… -
Imınlere asımetrık katılmalar
İnce, Akın (Kırıkkale Üniversitesi, 2010)Bu çalışmada Tosil imine asimetrik olarak dietilçinko, nitrometan (Aza-Henry) ve propargil katılması çalışılmıştır. Yapılan asimetrik reaksiyonlarda kiral ligand olarak FAM ve P-FAM katalizörleri kullanılmıştır. Çalışmada ... -
Karbonhidratların yeni tosil, azid ve amin türevleri sentezleri
Bulut, Adnan; Kırıkkale Üniversitesi, Rektörlük, Projeler (KırıkkaleKırıkkale Üniversitesi, 2014)… -
Kiral heteroril ferrosenil alkollerin sentezi ve biyolojik aktivitesinin incelenmesi
Bulut, Adnan; Kırıkkale Üniversitesi, Rektörlük, Projeler (KırıkkaleKırıkkale Üniversitesi, 2017)… -
New zinc(II)-based catalyst for asymmetric azomethine ylide cycloaddition reactions
Doğan, Özdemir; Koyuncu, Hasan; Garner, Philip; Bulut, Adnan; Youngs, Wiley J.; Panzner, Matthew (Amer Chemical Soc, 2006)A new chiral aziridino alcohol ligand for zinc(II)-catalyzed azomethine ylide cycloadditions is described. In the presence of this catalyst, N-arylidene glycine methyl esters react with a variety of dipolarophiles to give ... -
Non-Acidic Mediated Friedel-Craft Reaction of Thiophene Using EtAlCl2
Unver, Halil; Biyikoglu, Mutluhan; Bulut, Adnan (Asian Journal Of Chemistry, 2013)Since alkyl Lewis acids are Bronsted bases, they give a non-acidic reaction media. In this context, acylation of thiophene is investigated in the presence of EtAlCl2 and non-acidic media. Besides 8 examples of thiophene, ... -
ORGN 188-A new method for the synthesis of racemic and chiral aziridine 2-phosphonates
Doğan, Özdemir; Bulut, Adnan; Aslan, Ayhan; Tan, Serkan; Babiz, Hakan (Amer Chemical Soc, 2009)… -
Pyrolysis of Table Sugar
Bulut, Adnan; Karagoz, Selhan (Hindawi Publishing Corporation, 2013)Table sugars were pyrolyzed at different temperatures (300, 400, and 500 degrees C) in a fixed-bed reactor. The effect of pyrolysis temperature on yields of liquid, solid, and gaseous products was investigated. As expected ...
