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Chiral phosphine oxide aziridinyl phosphonate as a Lewis base catalyst for enantioselective allylsilane addition to aldehydes
Dogan, Ozdemir; Bulut, Adnan; Tecimer, M. Ali (Pergamon-Elsevier Science Ltd, 2015)A series of chiral Lewis bases, phosphine oxide ferrocenyl aziridinyl methanol 1-4, phosphinyl aziridinyl phosphonates 5 and 6, and phosphine oxide aziridinyl phosphonates 7 and 8 were screened for allylsilane additions ... -
Copper-catalyzed asymmetric conjugate addition of diethylzinc to substituted chalcones using a chiral phosphine ligand
Dogan, Ozdemir; Bulut, Adnan; Polat, Savas; Tecimer, M. Ali (Pergamon-Elsevier Science Ltd, 2011)A series of chiral phosphine PFAM and phosphine oxide POFAM ligands were studied for the copper-catalyzed asymmetric diethylzinc addition to enones. One of these ligands, PFAM2, was an efficient catalyst with a variety of ...