Güncel Gönderiler: Kimya Bölümü
Toplam kayıt 245, listelenen: 181-200
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Ring opening polymerization of 2,5-dihydro-2,5-dimethoxyfuran by electrochemical initiation
(Springer, 2004)2,5-Dihydro-2,5-dimethoxyfuran (DHMF) was polymerized via constant current electrolysis (CCE), in CH3CN-NaClO4 solvent-electrolyte couple. Poly(DHMF) was obtained from the anolyte. The effect of current density, temperature, ... -
Affinity membrane chromatography: relationship of dye-ligand type to surface polarity and their effect on lysozyme separation and purification
(Elsevier, 2004)Two different dye-ligands, i.e. Procion Brown MX-5BR (RB-10) and Procion Green H-4G (RG-5) were immobilised onto poly(2-hydroxyethylmethacrylate) (pHEMA) membranes. The polarities of the affinity membranes were determined ... -
Biosorption of Hg2+, Cd2+, and Zn2+ by Ca-alginate and immobilized wood-rotting fungus Funalia trogii
(Elsevier, 2004)Funalia trogii biomass was immobilized in Ca-alginate gel beads. The live and beat inactivated immobilized forms were used for the biosorption of Hg2+, Cd2+ and Zn2+ ions by using plain Ca-alginate gel beads as a control ... -
Phosphorus-nitrogen compounds. spiro- and crypta-phosphazene derivatives: synthesis and spectral investigations. Structure of butane- N, N'-bis(1,4-oxybenzyl)- spiro(propane-1,3-diamino)tetrachlorocyclo-2λ 5, 4λ 5, 6λ 5-triphosphazatriene. Part VII
(Elsevier, 2004)The condensation reactions between trimer, N3P3Cl6, and diamines, 2 and 4 and {1-{N-[1-(2-hydroxynaphthylmethyl)aminomethylidene]}-2(1H)-naphthalenone, 3, yielded the new spiro-cyclic- (5 and 8) and the novel spiro-phosphazene ... -
Evaluation of lysozyme adsorptive behaviour of pHEMA-based affinity membranes related to the surface energy and its components to be used in chromatographic fields
(Elsevier, 2004)We have studied the influence of the surface energy and its components of two different dye-ligand immobilised poly(hydroxyethylmethacrylate) (pHEMA) membranes to the adsorption of a protein "lysozyme" from aqueous solutions. ... -
Preparation and characterisation of surfaces properties of poly(hydroxyethylmethacrylate-co-methacrylolyamido-histidine) membranes: application for purification of human immunoglobulin G
(Elsevier, 2004)In this study, an affinity membrane containing L-histidine as an amino acid ligand was used in separation and purification of human immunoglobulin G (HIgG) from solution and human serum. The polarities and the surface free ... -
Polyethyleneimine-grafted poly (hydroxyethyl methacrylate-co-glycidyl methacrylate) membranes for reversible glucose oxidase immobilization
(Elsevier Science Sa, 2004)Glucose oxidase (GOD) was immobilized onto polyethyleneimide (PEI) grafted poly(hydroxyethyl methacrylate-co-glycidyl methacrylate) (poly(HEMA-co-GMA)) membranes. The maximum GOD immobilization capacities of the ... -
Surface properties of Reactive Yellow 2 immobilised pHEMA and HEMA/chitosan membranes: characterisation of their selectivity to different proteins
(Elsevier, 2004)Poly(hydroxyethyl methacrylate), pHEMA, and a composite pHEMA/chitosan networks were synthesized in the membrane form via UV initiated photo-polymerisation in the presence of an initiator alpha,alpha'-azoisobutyronitrile. ... -
Permeation and separation characteristics of acetic acid/water mixtures through poly(vinyl alcohol-g-itaconic acid) membranes by pervaporation, evapomeation, and temperature-difference evapomeation
(Wiley, 2004)In this study, itaconic acid (IA) was grafted onto poly(vinyl alcohol) (PVA) with cerium(IV) ammonium nitrate as an initiator at 45degreesC. The grafted PVA was characterized with Fourier transform infrared spectroscopy, ... -
Characterisation of tyrosinase immobilised onto spacer-arm attached glycidyl methacrylate-based reactive microbeads
(Elsevier Sci Ltd, 2004)Immobilisation of tyrosinase onto modified poly(methyl methacrylate-glycidyl methacrylate-divinyl benzene), poly(MMA-GMA-DVB), microbeads was studied. The epoxy group containing poly(MMA-MMA-DVB) microbeads were prepared ... -
Preparation and application of spacer-arm-attached poly (hydroxyethyl methacrylate-co-glycidyl methacrylate) films for urease immobilisation
(Elsevier Science Bv, 2003)Immobilisation of urease onto plain and six-carbon spacer-arm (i.e. 1,6-diaminohexane) attached poly(hydroxyethyl methacrylate-co-glycidyl methacrylate) [poly (HEMA-GMA)] films was studied. The epoxy groups containing ... -
Thermal behaviour of alumina precursor obtained by the aluminium sulphate-urea reaction in boiling aqueous solution
(Elsevier Sci Ltd, 2003)An aqueous solution containing 0.1 M Al3+ and excess urea was boiled for 4 h to obtain an alumina precursor precipitate. The precursor precipitate was separated into several portions and each portion was heated at a different ... -
Affinity dye-ligand poly(hydroxyethyl methacrylate)/chitosan composite membrane for adsorption lysozyme and kinetic properties
(Elsevier Science Sa, 2003)A composite membrane from 2-hydroxyethyl methacrylate (HEMA) and poly(hydroxyethyl methacrylate)/chitosan (pHEMA/chitosan) was synthesized via UV initiated photo-polymerization in the presence of an initiator alpha,alpha ... -
Procion Green H-4G immobilized poly(hydroxyethylmethacrylate/chitosan) composite membranes for heavy metal removal
(Elsevier Science Bv, 2003)The effective removal of toxic heavy metals from environmental samples still remains a major topic of present research. Metal-chelating membranes are very promising materials as adsorbents when compared with conventional ... -
Tetrakis(μ3-phenoxo-acetonitrilelithium), a tetrameric lithium aryloxide with a cubane core
(Int Union Crystallography, 2003)The title compound, (CH3CNLiOC6H5)(4) or [Li-4 (C6H5O)(4) (C2H3N)(4)], is tetrameric with a distorted Li4O4 cube core. The molecule has crystallographic (4) over bar symmetry. Each Li atom has distorted tetrahedral ... -
Ca-alginate as a support for Pb(II) and Zn(II) biosorption with immobilized Phanerochaete chrysosporium
(Elsevier Sci Ltd, 2003)The basidio spores of Phanerochaete chryosporium were immobilized in alginate gel beads, and the immobilized spore containing alginate beads were incubated for the growth of fungus. The biosorption of Pb2+ and Zn2+ ions ... -
Covalent immobilisation of invertase onto a reactive film composed of 2-hydroxyethyl methacrylate and glycidyl methacrylate: properties and application in a continuous flow system
(Elsevier Science Sa, 2003)Invertase was covalently immobilised on the poly(hydroxyethyl methacrylate-co-glycidyl methacrylate) (poly(HEMA-GMA)) film. The invertase immobilisation capacity of the films was increased as the GMA ratio increased in the ... -
Poly(2-hydroxyethylmethacrylate)/chitosan dye and different metal-ion-immobilized interpenetrating network membranes: Preparation and application in metal affinity chromatography
(John Wiley & Sons Inc, 2003)Composite membranes were synthesized with 2-hydroxyethylmethacrylate and chitosan (pHEMA/chitosan) via an ultraviolet-initiated photopolymerization technique in the presence of an initiator (alpha,alpha'-azobisisobutyronitrile). ... -
DNA adsorption on a poly-L-lysine-immobilized poly(2-hydroxyethyl methacrylate) membrane
(Wiley, 2003)The DNA adsorption properties of poly-L-lysine-immobilized poly(2-hydroxyethyl methacrylate) (pHEMA) membrane were investigated. The pHEMA membrane was prepared by UV-initiated photopolymerization and activated with ... -
An alkoxide cluster with 18 Li+ ions encapsulating two borate anions, [(tBuO)12Li18(BO3)2]
(Blackwell Munksgaard, 2003)The title compound, bis(borato) dodeca(tert-butoxo)octadeca-lithium, [Li-18(BO3)(2)(C4H9O)(12)], is formulated conveniently as [{((BuOLi)-Bu-t)(3)(Li3BO3)}(2)((BuOLi)-Bu-t)(6)]. A central 12-membered ring and two outer ...