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dc.contributor.authorÜnver, Halil
dc.contributor.authorÖktem, Zeki
dc.date.accessioned2020-06-25T18:07:19Z
dc.date.available2020-06-25T18:07:19Z
dc.date.issued2013
dc.identifier.citationclosedAccessen_US
dc.identifier.issn0014-3057
dc.identifier.issn1873-1945
dc.identifier.urihttps://doi.org/10.1016/j.eurpolymj.2013.01.025
dc.identifier.urihttps://hdl.handle.net/20.500.12587/5543
dc.descriptionWOS: 000317882600007en_US
dc.description.abstractCuCl/N,N,N',N '',N ''-pentamethyldiethylenetriamine catalyst system was used successfully in the controlled cationic polymerization of furfuryl alcohol initiated with benzyl bromide in acetonitrile. Polymerizations were carried out at 110 degrees C open to air. The effect of reaction time, amount of initiator and solvent on the rate of polymerization was studied. The linear kinetic plot of In([M](o)/[M]) versus polymerization time, linear dependence of the molecular weight on the monomer conversion and low polydispersity of the polymers (1.07-1.50) showed the characteristics of the controlled polymerization. Soluble polymers with M-n up to 6.6 kg/mol were obtained. The structural analysis of the polymer was carried out by H-1 NMR, C-13 NMR, FTIR and UV-VIS spectroscopies. Formation of carbonyl groups and -CH2-O-CH2- bridges on poly(furfuryl alcohol) chains were observed. Thermal properties of the polymer were studied by DSC and TGA analyses. (C) 2013 Elsevier Ltd. All rights reserved.en_US
dc.description.sponsorshipKirikkale UniversityKirikkale University [BAP-2010/9]en_US
dc.description.sponsorshipThe authors are grateful to Kirikkale University Research Fund, BAP-2010/9, for support of this work.en_US
dc.language.isoengen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.isversionof10.1016/j.eurpolymj.2013.01.025en_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCationic polymerizationen_US
dc.subjectControlled cationic polymerizationen_US
dc.subjectFurfuryl alcoholen_US
dc.subjectCuCl/PMDETAen_US
dc.titleControlled cationic polymerization of furfuryl alcoholen_US
dc.typearticleen_US
dc.contributor.departmentKırıkkale Üniversitesien_US
dc.identifier.volume49en_US
dc.identifier.issue5en_US
dc.identifier.startpage1023en_US
dc.identifier.endpage1030en_US
dc.relation.journalEuropean Polymer Journalen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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