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  • Küçük Resim
    Öğe
    Application of FAM ligands in the metal-promoted catalytic enantioselective synthesis of organic compounds
    (Scientific Technical Research Council Turkey-Tubitak, 2009) Dogan, Oezdemir; Garner, Philip P.; Bulut, Adnan
    Novel ferrocenyl substituted aziridinyl methanol (FAM) ligands were synthesized and successfully used in metal-promoted catalytic enantioselective azomethine ylide cycloadditions, diethylzinc additions to enones, alkynylzinc additions to aldehydes, diethylzinc additions to aldehydes, and Henry reactions. These reactions are summarized in this report.
  • [ X ]
    Öğe
    Catalytic asymmetric nitroaldol (Henry) reaction with a zinc-Fam catalyst
    (Amer Chemical Soc, 2008) Bulut, Adnan; Aslan, Ayhan; Dogan, Oezdemir
    Ferrocenyl-substituted aziridinylmethanol (Fam-1) was used as a catalyst with zinc for the asymmetric nitroaldol (Henry) reaction. This catalyst worked with a variety of aldehydes (aromatic, aliphatic, alpha,beta-unsaturated, and heteroaromatic) and alpha-ketoesters to give the nitroaldol product in up to 97% yield and 91% ee. The chiral ligand call be recovered and recycled Without losing its activity.