Catalytic asymmetric nitroaldol (Henry) reaction with a zinc-Fam catalyst
[ X ]
Tarih
2008
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Amer Chemical Soc
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Ferrocenyl-substituted aziridinylmethanol (Fam-1) was used as a catalyst with zinc for the asymmetric nitroaldol (Henry) reaction. This catalyst worked with a variety of aldehydes (aromatic, aliphatic, alpha,beta-unsaturated, and heteroaromatic) and alpha-ketoesters to give the nitroaldol product in up to 97% yield and 91% ee. The chiral ligand call be recovered and recycled Without losing its activity.
Açıklama
Anahtar Kelimeler
Kaynak
Journal Of Organic Chemistry
WoS Q Değeri
Q1
Scopus Q Değeri
Q2
Cilt
73
Sayı
18
Künye
closedAccess
