Catalytic asymmetric nitroaldol (Henry) reaction with a zinc-Fam catalyst

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dc.contributor.authorBulut, Adnan
dc.contributor.authorAslan, Ayhan
dc.contributor.authorDogan, Oezdemir
dc.date.accessioned2020-06-25T17:44:20Z
dc.date.available2020-06-25T17:44:20Z
dc.date.issued2008
dc.departmentKırıkkale Üniversitesi
dc.description.abstractFerrocenyl-substituted aziridinylmethanol (Fam-1) was used as a catalyst with zinc for the asymmetric nitroaldol (Henry) reaction. This catalyst worked with a variety of aldehydes (aromatic, aliphatic, alpha,beta-unsaturated, and heteroaromatic) and alpha-ketoesters to give the nitroaldol product in up to 97% yield and 91% ee. The chiral ligand call be recovered and recycled Without losing its activity.en_US
dc.description.sponsorshipScientific and Technical Research Council of TurkeyTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [TBAG-106T071]; Middle East Technical UniversityMiddle East Technical University; Kirikkale University Research FoundationsKirikkale Universityen_US
dc.description.sponsorshipThe authors thank the Scientific and Technical Research Council of Turkey (TUBITAK. Grant No. TBAG-106T071), Middle East Technical University, and Kirikkale University Research Foundations for financial support.en_US
dc.identifier.citationclosedAccessen_US
dc.identifier.doi10.1021/jo8010073
dc.identifier.endpage7375en_US
dc.identifier.issn0022-3263
dc.identifier.issue18en_US
dc.identifier.pmid18700743
dc.identifier.scopus2-s2.0-52449112922
dc.identifier.scopusqualityQ2
dc.identifier.startpage7373en_US
dc.identifier.urihttps://doi.org/10.1021/jo8010073
dc.identifier.urihttps://hdl.handle.net/20.500.12587/4081
dc.identifier.volume73en_US
dc.identifier.wosWOS:000259195200058
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherAmer Chemical Socen_US
dc.relation.ispartofJournal Of Organic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleCatalytic asymmetric nitroaldol (Henry) reaction with a zinc-Fam catalysten_US
dc.typeArticle

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