Synthesis, characterization and radical polymerization of novel furan substituted acrylamide

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dc.contributor.authorTombul M.
dc.contributor.authorBulut A.
dc.contributor.authorÜnver H.
dc.date.accessioned2020-06-25T15:17:53Z
dc.date.available2020-06-25T15:17:53Z
dc.date.issued2017
dc.departmentKırıkkale Üniversitesi
dc.description.abstractN-[(Furan-2-yl)methyl]acrylamide (FMA) was synthesized via the reaction of furfurylamine with acryloyl chloride and the chemical structure was elucidated by 1H NMR, 13C NMR and FTIR analyses. Free radical polymerization of N-[(furan-2-yl)methyl]acrylamide was performed employing benzoyl peroxide (BPO) initiator under inert atmosphere of nitrogen in toluene. The monomer concentration and initiator concentration ranges were 8.8 × 10-2 to 13.2 × 10-2 mol L-1 and 3.4 × 10-3 to 20.7 × 10-3 mol L-1, respectively. The rate of polymerization (Rp) was found to be Rp = k[BPO]0.51[FMA]1.69. The overall activation energy of 84 kJ mol-1 was obtained in the temperature range 70-90°C. The FTIR spectra of the prepared polymer indicate disappearance of the band at 1620 cm-1, which is basically due to the olefinic C=C stretching, confirming the polymerization of N-[(furan-2-yl)methyl]acrylamide. © 2017, Chemical Publishing Co. All rights reserved.en_US
dc.identifier.doi10.14233/ajchem.2017.20283
dc.identifier.endpage460en_US
dc.identifier.issn09707077
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-85009936558
dc.identifier.scopusqualityQ4
dc.identifier.startpage457en_US
dc.identifier.urihttps://doi.org/10.14233/ajchem.2017.20283
dc.identifier.urihttps://hdl.handle.net/20.500.12587/2560
dc.identifier.volume29en_US
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherChemical Publishing Co.en_US
dc.relation.ispartofAsian Journal of Chemistry
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectArylamideen_US
dc.subjectFuranen_US
dc.subjectRadical polymerizationen_US
dc.titleSynthesis, characterization and radical polymerization of novel furan substituted acrylamideen_US
dc.typeArticle

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