Crystal structure and physico-chemical properties of diaquabis(1,10-phenanthroline)manganese(II) disaccharinate monohydrate

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dc.contributor.authorYılmaz, VT..
dc.contributor.authorYiımaz, F.
dc.contributor.authorTopcu, Y.
dc.contributor.authorAndac, O.
dc.contributor.authorGüven, K.
dc.date.accessioned2020-06-25T17:34:53Z
dc.date.available2020-06-25T17:34:53Z
dc.date.issued2001
dc.departmentKırıkkale Üniversitesi
dc.descriptionTOPCU, YILDIRAY/0000-0002-2095-6603; Andac, Omer/0000-0003-3641-9690; Yilmaz, Veysel/0000-0002-2849-3332; YILMAZ, Fatih/0000-0002-7711-0975
dc.description.abstractA novel manganese complex, [Mn(phen)(2)(H2O)(2)](sac)(2).H2O, was synthesized by the reaction of [Mn(sac)(2)(H2O)(4)]. 2H(2)O with 1,10-phenantroline in aqueous solution and characterized by elemental analysis, IR spectral evidence, magnetic measurements, thermal analysis and single crystal X-ray diffraction. The compound crystallizes in triclinic system, space group P-1, with Z = 2. The saccharinate ions do not coordinate the central metal, instead are present as the complementary anions. In the complex cation, Mn(II) is coordinated by two phen and two aqua ligands, and exhibits a distorted octahedral coordination with a high-spin configuration. The presence of lattice and coordinate water molecules are also confirmed by thermal analysis and IR spectroscopy. (C) 2001 Elsevier Science B.V. All rights reserved.en_US
dc.identifier.citationclosedAccessen_US
dc.identifier.doi10.1016/S0022-2860(00)00730-4
dc.identifier.endpage13en_US
dc.identifier.issn0022-2860
dc.identifier.issue1-3en_US
dc.identifier.startpage9en_US
dc.identifier.urihttps://doi.org/10.1016/S0022-2860(00)00730-4
dc.identifier.urihttps://hdl.handle.net/20.500.12587/2937
dc.identifier.volume560en_US
dc.identifier.wosWOS:000167079800002
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.language.isoen
dc.publisherElsevier Science Bven_US
dc.relation.ispartofJournal Of Molecular Structure
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectMn(II) complexesen_US
dc.subject1,10-phenantroline complexesen_US
dc.subjectsaccharinatesen_US
dc.subjectcrystal structureen_US
dc.subjectspectraen_US
dc.subjectthermal analysisen_US
dc.titleCrystal structure and physico-chemical properties of diaquabis(1,10-phenanthroline)manganese(II) disaccharinate monohydrateen_US
dc.typeArticle

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