2-Hidroksi-1 naftaldehidin primer aminlerle schiff bazlarının sentezi ve bazı geçiş metal komplekslerinin hazırlanması
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Tarih
1997
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Kırıkkale Üniversitesi
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
ÖZET Bu çalışmada, 2-Hidroksi-l-naftaldehitin metanol ortamında aromatik primer aminlerle etkileştirilmesi sonucu N-(2-piridil)-2-hidroksi-l-naftaldimin (C16H12N2O) (1), N-(4-metil-2-pridil)-2-hidroksi-l-naftaldimin (C17Hı3N20) (2) ve N~(6-metil-2-pridil)-2- hidroksi-l-naftaldimin(Ci7Hı5N20) (3) schiff bazları sentezlendi.Bu schiffbazı ligandları ile Zn(II), Co(II) ve Cu(II) kompleksleri hazırlandı.Ligandların ve komplekslerin yapıları FTIR, ^-NMR, element analizi,magnetik süsseptibilite ve X-ışınlan kristallografisi verilerinden faydalanılarak aydınlatıldı. Anahtar Kelimeler: 2-Hidroksi-l-naftaldehit, Schiff bazları, Schiffbazı kompleksleri.
Ill ABSTRACT In this study, N-(2-pyridyl)-2-hydroxy-l-naphtaIdimine(l), N-(4-methyl-2- pyridyl)~2-hydroxy- l-naphtaldimine(2) and N-(6-methyl-2-pyridyl)-2-hydroxy- 1 - naphtaldimine (3) schiff bases were synthezided by reaction of 2-hydroxy-l- naphthaldehyde with aromatic primary amines in methanol.Using these schiff base ligands Zn(II), Co(II) and Cu(II) complexes were prepared. The structure of the ligands and their complexes were determined by elemental analyses, magnetic susseptibility, FTIE^H-NMR spectral data and X-ray Crystallograpy. Key words: 2-Hydroxy-l-naphthaldehyde, Schiff bases, Schiff base complexes.
Ill ABSTRACT In this study, N-(2-pyridyl)-2-hydroxy-l-naphtaIdimine(l), N-(4-methyl-2- pyridyl)~2-hydroxy- l-naphtaldimine(2) and N-(6-methyl-2-pyridyl)-2-hydroxy- 1 - naphtaldimine (3) schiff bases were synthezided by reaction of 2-hydroxy-l- naphthaldehyde with aromatic primary amines in methanol.Using these schiff base ligands Zn(II), Co(II) and Cu(II) complexes were prepared. The structure of the ligands and their complexes were determined by elemental analyses, magnetic susseptibility, FTIE^H-NMR spectral data and X-ray Crystallograpy. Key words: 2-Hydroxy-l-naphthaldehyde, Schiff bases, Schiff base complexes.
Açıklama
Anahtar Kelimeler
Kimya, Chemistry, Aminler, Amines ; Geçiş metalleri, Transition metals ; Metal kompleksleri, Metal complexes ; Schiff bazları, Schiff bases
