Electrochemical polymerization of 4-allylanisole

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dc.contributor.authorCihaner, Atilla
dc.contributor.authorTestereci, Hasan Nur
dc.contributor.authorÖnal, Ahmet M.
dc.date.accessioned2020-06-25T17:34:49Z
dc.date.available2020-06-25T17:34:49Z
dc.date.issued2001
dc.departmentKırıkkale Üniversitesi
dc.descriptionOnal, Ahmet M./0000-0003-0644-7180
dc.description.abstractElectrochemical polymerization of 3-allylanisole (4AA). via constant potential electrolysis, has been investigated in acetonitrile using two different supporting electrolytes. Redox behavior of the monomer was also studied in the same solvent-electrolyte couples at room temperature. Electrochemical polymerization of the monomer yielded insoluble polymer films on the electrode surface, which bears a very low conductivity, together with the low molecular weight polymers in the bulk of the solution. The decrease in the monomer concentration, during the electrochemical polymerization. was monitored by taking the cyclic voltammogram of the electrolysis solution. The effect of temperature on the rate of electrochemical polymerization was: also studied. The polymers were characterized by taking the H-1-NMR and FTIR spectra. Molecular weight of the soluble polymer was determined by vapor pressure osmometry. Thermal analysis of the polymer film and soluble polymer were done by DSC. (C) 2001 Elsevier Science Ltd. All rights reserved.en_US
dc.identifier.citationclosedAccessen_US
dc.identifier.doi10.1016/S0014-3057(01)00065-9
dc.identifier.endpage1752en_US
dc.identifier.issn0014-3057
dc.identifier.issue9en_US
dc.identifier.scopus2-s2.0-0035452701
dc.identifier.scopusqualityQ1
dc.identifier.startpage1747en_US
dc.identifier.urihttps://doi.org/10.1016/S0014-3057(01)00065-9
dc.identifier.urihttps://hdl.handle.net/20.500.12587/2907
dc.identifier.volume37en_US
dc.identifier.wosWOS:000169806400004
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofEuropean Polymer Journal
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject4-allylanisoleen_US
dc.subjectelectrochemical polymerizationen_US
dc.subjectcyclic voltammetryen_US
dc.subjectconstant potential electrolysisen_US
dc.titleElectrochemical polymerization of 4-allylanisoleen_US
dc.typeArticle

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