Synthesis and crystal structure of bis[N-(2-fluoro-3-methoxy)-salicylideneaminato]copper(II)
Yükleniyor...
Tarih
2003
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Kluwer Academic/Plenum Publ
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The title compound, bis[N-(2-fluoro-3-methoxy)-salicylideneaminato] copper(II) [Cu(C14H12O2FN)(2)] was synthesized and its crystal structure was determined. The title compound is triclinic, space group P (1) over bar with a = 8.552(1), b = 9.645(1), c = 7.871(1) Angstrom, alpha = 108.708(1), beta = 93.769(1), gamma = 79.429(1)degrees, V = 1208.98(1) Angstrom(3), Z = 2, D-c = 1.696 g.cm(-3), mu(Mo Kalpha) = 1.815 mm(-1), R = 0.0369 for 2963 reflections [I > 2sigma(I)]. The title compound has crystallographic inversion symmetry with two bidentate Schiff base ligand coordinated to the Cu atom in a square-planar arrangement. The Cu-N1 and Cu-O2 distances are 1.995(1) and 1.885(1) Angstrom, respectively.
Açıklama
Unver, Huseyin/0000-0003-3968-4385
Anahtar Kelimeler
Schiff base complex, crystal structure, coordination geometry, inversion symmetry
Kaynak
Journal Of Chemical Crystallography
WoS Q Değeri
Q4
Scopus Q Değeri
Q3
Cilt
33
Sayı
4
Künye
closedAccess
