Development and characterization of lithium salts doped nanoconductive ROMP polymers
Yükleniyor...
Tarih
2010
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier Science Sa
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The work presented in this paper describes a new technique for the design and synthesis of nanoconductive polymers. These nanoconductive materials were based on the ROMP of norbornene monomers with oxygen in the 7-position using Grubbs ruthenium initiator, Ru(=CHPh)(PCy(3))(2)Cl(2), and mixing the resulting polymer with various inorganic salts such as LiBF(4), LiPF(6). LiA(5)F(6) and LiSbF(6). The norbornene derivative monomers and the corresponding ROMP polymers were fully characterized by spectral methods. The ROMP polymers containing inorganic salts were investigated by ESEM (environmental scanning electron microscopy) for the formation of nano-structures. The distribution of the lithium salts within the polymer matrix was determined by IBA analysis. The conductivity measurements were carried out on thin films of the ROMP polymers containing inorganic salts. (C) 2010 Elsevier B.V. All rights reserved.
Açıklama
Anahtar Kelimeler
ROMP, Conducting polymers, Solid polymer electrolyte, Nanomaterials, Lithium salts
Kaynak
Synthetic Metals
WoS Q Değeri
Q2
Scopus Q Değeri
Q1
Cilt
160
Sayı
9-10
Künye
closedAccess
