Application of well-defined ruthenium alkylidenes to the ROMP of norbornene derivatives: Methoxyphenyl-substituted polynorbornene dicarboximides

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dc.contributor.authorCetinkaya, Sevil
dc.contributor.authorOzker, Taner
dc.contributor.authorBayram, Rifat
dc.date.accessioned2020-06-25T17:51:59Z
dc.date.available2020-06-25T17:51:59Z
dc.date.issued2011
dc.departmentKırıkkale Üniversitesi
dc.description.abstractThe applicability of ruthenium alkylidenes as initiators in the ring opening metathesis polymerization (ROMP) of methoxyphenyl group containing norbornene derivatives has been investigated. The synthesis and polymerization of exo-N-4-methoxyphenyl-oxanorbornene-5,6-dicarboximide (MeOPhONDI) and exo-N-4-methoxyphenyl-norbornene-5,6-dicarboximide (MeOPhNDI) are reported. Polynorbornene derivatives were obtained via ROMP using first- and second-generation ruthenium alkylidene initiators. The structural properties of the polynorbornene derivatives were analyzed by NMR, DSC and GPC. Analyses of the polymer microstructures indicate that polymers contain trans stereoconfiguration of the double bonds (55-86% trans-content). The glass transition temperatures of the polymers obtained from exo-monomers are higher than 211 degrees C. (C) 2010 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipKirikkale University FoundationKirikkale University [2009/34]en_US
dc.description.sponsorshipWe thank the Kirikkale University Foundation (Project No.: 2009/34) for the financial support of this work.en_US
dc.identifier.citationclosedAccessen_US
dc.identifier.doi10.1016/j.apcata.2010.11.021
dc.identifier.endpage28en_US
dc.identifier.issn0926-860X
dc.identifier.issue1-2en_US
dc.identifier.scopus2-s2.0-78951472728
dc.identifier.scopusqualityQ1
dc.identifier.startpage24en_US
dc.identifier.urihttps://doi.org/10.1016/j.apcata.2010.11.021
dc.identifier.urihttps://hdl.handle.net/20.500.12587/5049
dc.identifier.volume393en_US
dc.identifier.wosWOS:000287619400004
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Bven_US
dc.relation.ispartofApplied Catalysis A-General
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectMetathesisen_US
dc.subjectPolynorbornene dicarboximideen_US
dc.subjectROMPen_US
dc.subjectRuthenium alkylideneen_US
dc.subjectHomogeneous catalysisen_US
dc.titleApplication of well-defined ruthenium alkylidenes to the ROMP of norbornene derivatives: Methoxyphenyl-substituted polynorbornene dicarboximidesen_US
dc.typeArticle

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