Tautomeric properties and crystal structure of N-[2-hydroxy-1-naphthylidene]2,5-dichloroaniline

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dc.contributor.authorYıldız, Mustafa
dc.contributor.authorÜnver, Hüseyin
dc.contributor.authorErdener, Diğdem
dc.contributor.authorOcak, Nazan
dc.contributor.authorErdönmez, Ahmet
dc.contributor.authorDurlu, Tahsin Nuri
dc.date.accessioned2020-06-25T17:43:32Z
dc.date.available2020-06-25T17:43:32Z
dc.date.issued2006
dc.descriptionUnver, Huseyin/0000-0003-3968-4385
dc.description.abstractThe title compound has been synthesised by the reaction of 2-hydroxy-1-naphthaldehyde with 2,5-dichloroaniline. The compound was characterized by elemental analysis, IR and UV-Visible techniques. The UV-Visible spectra of the Schiff base with OH group in ortho position to the imino group was studied in polar and nonpolar solvents in acidic and basic media. The structure of compound has been examined cyrstallographically. It crystallizes in the or-thorhombic space group P2(1)2(1)2(1) with a = 6.059(1), b = 12.105(2) c = 20.006(2) angstrom, V = 1467.4(3) angstrom(3), D-x = 1.431 g.cm(-3) and Z = 4. The crystal structure was solved by direct methods and refined by full-matrix least squares. Molecule of the title compound N-[2-hydroxy-1-naphthylidene]2,5-dichloroaniline is nearly planar. The molecule contains a strong intramolecular N...H-O hydrogen bond between the imine and hydroxyl group [O1 and N1 = 2.540(4) angstrom]. (c) 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en_US
dc.identifier.citationclosedAccessen_US
dc.identifier.doi10.1002/crat.200510632
dc.identifier.endpage606en_US
dc.identifier.issn0232-1300
dc.identifier.issn1521-4079
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-33745663100
dc.identifier.scopusqualityQ3
dc.identifier.startpage600en_US
dc.identifier.urihttps://doi.org10.1002/crat.200510632
dc.identifier.urihttps://hdl.handle.net/20.500.12587/3771
dc.identifier.volume41en_US
dc.identifier.wosWOS:000238682900012
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofCrystal Research And Technology
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectcrystal structureen_US
dc.subjecttautomerismen_US
dc.subjectspectroscopic studiesen_US
dc.subjectUV-visibleen_US
dc.subjectFT-IRen_US
dc.titleTautomeric properties and crystal structure of N-[2-hydroxy-1-naphthylidene]2,5-dichloroanilineen_US
dc.typeArticle

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