A Sodium Supported Borate Ester: Synthesis, Spectral Characterization and Crystal Structure of dimeric Sodium Organoborate Complex [Na(py)][B(hyncaH22)2]2

Basit Öğe Kaydı
dc.contributor.authorTombul, Mustafa
dc.contributor.authorGuven, Kutalmis
dc.contributor.authorDurlu, Tahsin N.
dc.date.accessioned2020-06-25T17:48:24Z
dc.date.available2020-06-25T17:48:24Z
dc.date.issued2009
dc.departmentKırıkkale Üniversitesi
dc.description.abstractA dimeric sodium supported borate complex, [Na(py)][B(hyncaH(-2))(2)](2) (1) (py = pyridine, hynca = 1-hydroxynaphthalene-2-carboxylic acid), has been synthesised by the reaction of NaBH4 with two equivalents of hynca in anhydrous THF and following crystallization from py/H2O solution afforded borate ester derivative. The complex has been fully characterized by FT-IR in the solid state and by NMR (H-1 and C-13) spectroscopy and electrospray ionization mass spectrometry in solution. The molecular structure of the title compound was determined by single crystal X-ray diffraction. Structure analysis of complex 1 confirmed the presence of an anionic complex [B(hyncaH(-2))(2)](-) in which boron atom is coordinated simultaneously by two hynca ligands utilising both alkoxide and carboxylate groups for bonding. The Na atom is six- coordinate to five O atoms of hydroxy carboxylic acid and one pyridine N atom. Crystal data: crystal system, monoclinic, a = 10.971(3) angstrom, b = 6.839(3) angstrom, c = 30.545(5) angstrom, beta = 92.20(2)degrees, space group P2(1)/c (#14), V = 2,290( 1) angstrom(3), Z = 4.en_US
dc.description.sponsorshipKirikkale UniversityKirikkale Universityen_US
dc.description.sponsorshipThe authors gratefully acknowledge Kirikkale University for the financial support of this research.en_US
dc.identifier.citationclosedAccessen_US
dc.identifier.doi10.1007/s10870-008-9500-1
dc.identifier.endpage448en_US
dc.identifier.issn1074-1542
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-64549086296
dc.identifier.scopusqualityQ3
dc.identifier.startpage445en_US
dc.identifier.urihttps://doi.org/10.1007/s10870-008-9500-1
dc.identifier.urihttps://hdl.handle.net/20.500.12587/4439
dc.identifier.volume39en_US
dc.identifier.wosWOS:000265020200010
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer/Plenum Publishersen_US
dc.relation.ispartofJournal Of Chemical Crystallography
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSodium complexesen_US
dc.subjectBorate estersen_US
dc.subjectHydroxycarboxylic acidsen_US
dc.subjectCrystal structureen_US
dc.titleA Sodium Supported Borate Ester: Synthesis, Spectral Characterization and Crystal Structure of dimeric Sodium Organoborate Complex [Na(py)][B(hyncaH22)2]2en_US
dc.typeArticle

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
[ X ]
İsim:
A Sodium Supported Borate Ester Synthesis, Spectral Characterization and Crystal Structure of dimeric Sodium Organoborate Complex.pdf
Boyut:
242.27 KB
Biçim:
Adobe Portable Document Format
Açıklama:
Tam Metin/Full Text
İndir

Koleksiyon

WOS İndeksli Yayınlar Koleksiyonu
Makale Koleksiyonu
Makale Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu