Investigation of the electrochemical reduction mechanism of 1-[N-(2-pyridyl)aminomethylidene]-2(1H)-naphthalenone (PN)
Yükleniyor...
Tarih
2005
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier Science Sa
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The electrochemical reduction mechanism of 1-[N-(2-pyridyl)aminomethylidene]-2(1H)-naphthalenone (PN) was investigated by using various electrochemical techniques in 0.1 M tetrabutylammonium tetrafluoroborate (TBATFB) in acetonitrile at glassy carbon (GC) electrode. The number of electrons transferred and diffusion coefficient of the compound were estimated by using an ultra-microelectrode (UME). PN has two reduction peaks in a cyclic voltammogram. Each of them corresponds to a one-electron transfer. In this medium and at the GC electrode surface, the first peak was observed at about - 1.8 V (vs. Ag/Ag+) which is more stable and well defined compared to the second peak. It was determined by using cyclic voltammetry that PN is electroreduced by an EC mechanism. It was also explained by multicycle CV experiments and a dopamine test as well as by Raman spectroscopy that the homogenous chemical reaction is dimerization. The EC mechanism was also examined and the kinetics of this process were calculated by digital simulation. (c) 2005 Elsevier B.V. All rights reserved.
Açıklama
Anahtar Kelimeler
Schiff base, electrodimerization, cyclic voltammetry, digital simulation
Kaynak
Journal Of Electroanalytical Chemistry
WoS Q Değeri
Q1
Scopus Q Değeri
Q1
Cilt
581
Sayı
1
Künye
closedAccess
