Unprecedented Formation of Potassium Borate Based Carbonate from Chloral Hydrate, Potassium Carbonate and Boric Acid

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dc.contributor.authorTombul, Mustafa
dc.contributor.authorTurkmenoglu, Elmas
dc.contributor.authorShin, Onur
dc.date.accessioned2025-01-21T16:55:47Z
dc.date.available2025-01-21T16:55:47Z
dc.date.issued2021
dc.departmentKırıkkale Üniversitesi
dc.description.abstractThe structure of the reaction product of boric acid, chloral hydrate, and potassium carbonate in H2O, potassium bis(carbonato)borate hydrate K[B(CO2-mu-O-CO2)(2)]center dot 2H(2)O, was determined by X-ray crystallography. The compound crystallized in the orthorhombic system, and was characterized to be in the space group Aba2, with cell parameters of a = 11.0579(10)angstrom, b = 11.1695(10)A, c = 9.0504(9)angstrom, Z = 4, and V = 1117.83(18)angstrom(3). In the crystal structure, intermolecular O-H center dot center dot center dot O hydrogen bonds link the molecules into a supramolecular structure, in which they may be effective in stabilizing the structure. The B atom espouses a distorted tetrahedral geometry with four O atoms of carbonate ligands.
dc.description.sponsorshipKirikkale University
dc.description.sponsorshipThe authors acknowledge to Scientific and Technological Research Application and Research Center, Sinop University, Turkey, for the use of Bruker D8 QUEST diffractometer. The authors also very much appreciate the financial support by Kirikkale University.
dc.identifier.endpage47
dc.identifier.issn1883-3578
dc.identifier.scopus2-s2.0-85113180208
dc.identifier.scopusqualityQ4
dc.identifier.startpage45
dc.identifier.urihttps://hdl.handle.net/20.500.12587/25840
dc.identifier.volume37
dc.identifier.wosWOS:000682937800003
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherJapan Soc Analytical Chemistry
dc.relation.ispartofX-Ray Structure Analysis Online
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241229
dc.titleUnprecedented Formation of Potassium Borate Based Carbonate from Chloral Hydrate, Potassium Carbonate and Boric Acid
dc.typeArticle

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