Synthesis of High-T-g Polymers via ROMP of Oxanorbornene Dicarboximides with Halogen Groups

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dc.contributor.authorCetinkaya, Sevil
dc.contributor.authorBayram, Rifat
dc.date.accessioned2020-06-25T17:51:23Z
dc.date.available2020-06-25T17:51:23Z
dc.date.issued2010
dc.departmentKırıkkale Üniversitesi
dc.description.abstractThis paper describes the synthesis of exo-N-phenyl-7-oxanorbornene-5, 6-dicarboximides with different substituents at para positions in the aromatic ring and their polymerization by ring-opening metathesis polymerization (ROMP) leading to high-T-g polymers. Exo-N-4-chlorophenyl-7-oxanorbornene-5,6-dicarboximide (ClPhONDI, 3a), exo-N-4-bromophenyl-7-oxanorbornene-5,6-dicarboximide (BrPhONDI, 3b), and exo-N-4-iodophenyl-7-oxanorbomene-5,6-dicarboximide (1PhONDI, 3c) monomers were synthesized. Polynorbornene dicarboximides were obtained via ROMP using a first-generation ruthenium alkylidene catalyst, Cl-2(PCy3)(2)Ru(=CHPh). The resulting amorphous polymers with trans configuration of the double bonds were characterized by NMR, SEM, DSC, and GPC. (C) 2010 Wiley Periodicals, Inc. Heteroatom Chem 21:36-43, 2010; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20576en_US
dc.description.sponsorshipKirikkale University Research FundKirikkale University [BAP 2007/56]en_US
dc.description.sponsorshipContract grant sponsor: Kirikkale University Research Fund.; Contract grant number: BAP 2007/56.en_US
dc.identifier.citationclosedAccessen_US
dc.identifier.doi10.1002/hc.20576
dc.identifier.endpage43en_US
dc.identifier.issn1042-7163
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-77749320840
dc.identifier.scopusqualityQ4
dc.identifier.startpage36en_US
dc.identifier.urihttps://doi.org/10.1002/hc.20576
dc.identifier.urihttps://hdl.handle.net/20.500.12587/4835
dc.identifier.volume21en_US
dc.identifier.wosWOS:000275759500004
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley-Blackwellen_US
dc.relation.ispartofHeteroatom Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleSynthesis of High-T-g Polymers via ROMP of Oxanorbornene Dicarboximides with Halogen Groupsen_US
dc.typeArticle

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