A Three Dimensional Lead(II) Polymer with Bridging Saccharinate and Unusually Coordinated Acetate Ligands Synthesis, IR Spectra, and Crystal Structure of [Pb(H2O)(µ-OAc)(µ-sac)]n

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dc.contributor.authorYilmaz, V.T.
dc.contributor.authorHamamci, S.
dc.contributor.authorAndaç, O.
dc.contributor.authorGüven, K.
dc.date.accessioned2020-06-25T17:35:44Z
dc.date.available2020-06-25T17:35:44Z
dc.date.issued2003
dc.departmentKırıkkale Üniversitesi
dc.descriptionAndac, Omer/0000-0003-3641-9690; Yilmaz, Veysel/0000-0002-2849-3332;
dc.description.abstractThe complex [Pb(H2O)(mu-OAc)(mu-sac)]n with acetate (OAc) and saccharinate (sac) ligands was characterized by IR, elemental analysis and X-ray crystallography The mixed-anion lead(II) complex crystallizes in the triclinic crystal system with the space group of P1. The single crystal X-ray analysis shows that the complex is a coordination polymer in which the lead(II) ions have a highly distorted pentagonal bipyramidal coordination geometry. Lead(II) ions are bridged by carboxylate groups in a zigzag arrangement forming one-dimensional infinite chains, which are also linked by sac bridges and aromatic pi-pi contacts between the adjacent phenyl rings of sac ligands, resulting in a three-dimensional network. One water molecule coordinates the lead(II) ion and also forms weak hydrogen bonds with the sulfonyl oxygen atoms of the neighboring sac ligands. The sac ligand acts as a bridging ligand through the nitrogen and carbonyl oxygen atoms, while the carboxylate moiety of the acetate ligand shows an unusual (bidentate, and bridging) coordination behaviour, which was observed for the first time in the structure.en_US
dc.identifier.citationclosedAccessen_US
dc.identifier.doi10.1002/zaac.200390011
dc.identifier.endpage176en_US
dc.identifier.issn0044-2313
dc.identifier.issn1521-3749
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-0037257312
dc.identifier.scopusqualityQ3
dc.identifier.startpage172en_US
dc.identifier.urihttps://doi.org/10.1002/zaac.200390011
dc.identifier.urihttps://hdl.handle.net/20.500.12587/3196
dc.identifier.volume629en_US
dc.identifier.wosWOS:000182160800025
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofZeitschrift Fur Anorganische Und Allgemeine Chemie
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectleaden_US
dc.subjectacetateen_US
dc.subjectsaccharinateen_US
dc.subjectpolymeric structureen_US
dc.titleA Three Dimensional Lead(II) Polymer with Bridging Saccharinate and Unusually Coordinated Acetate Ligands Synthesis, IR Spectra, and Crystal Structure of [Pb(H2O)(µ-OAc)(µ-sac)]nen_US
dc.typeArticle

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