Novel magnetic poly(allyl methacrylate-co-glycidyl methacrylate) Fe3O4 nanoparticles: synthesis and evaluation as adsorbents for heavy metals

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dc.authoriderduran, nuran/0000-0002-3920-0830
dc.authoridISILAR, OZER/0000-0001-7547-2537
dc.contributor.authorErduran, Nuran
dc.contributor.authorIsilar, Ozer
dc.date.accessioned2025-01-21T16:42:56Z
dc.date.available2025-01-21T16:42:56Z
dc.date.issued2024
dc.departmentKırıkkale Üniversitesi
dc.description.abstractMagnetic nanoparticles have gained significant attention as versatile adsorbents in various studies due to their easy application, simple synthesis, cost-effectiveness, and reusability. In this study, we synthesized magnetic poly(AMA-co-GMA) nanoparticles (MAG) and modified them using allyl methacrylate (AMA) and glycidyl methacrylate (GMA). The epoxy groups on the nanoparticles were opened to introduce -OH, -NH2, and -SH functional groups. The structural properties of the synthesized nanoparticles were characterized by FTIR, their morphology by SEM-EDS, TEM, BET, and XRD, their magnetic properties by VSM, and the thermal properties by the TGA analysis. MAG and the modified nanoparticles (MAG-OH, MAG-NH2, and MAG-SH) were then employed in batch adsorption experiments for heavy metal ions, including Cd2+, Cu2+, Zn2+, Ni2+, Pb2+, and Hg2+. The effect of pH, contact time, ion concentration, and temperature on adsorption was investigated, and kinetic, isotherm, and thermodynamic parameters were determined. Pb2+ and Hg2+ exhibited higher adsorption capacities among the tested heavy metal ions, prompting further investigation with MAG and MAG-SH nanoparticles. The experimental data suggested that the adsorption followed the second order kinetic and Langmuir isotherm models. Overall, the results highlight the excellent potential of the synthesized magnetic nanoparticles for effectively removing heavy metal ions from wastewater.
dc.description.sponsorshipKirikkale University [2020/089]; Scientific Research Projects Coordination Unit of Kimath;rimath;kkale University
dc.description.sponsorshipThis work was supported by Scientific Research Projects Coordination Unit of K & imath;r & imath;kkale University. Project number 2020/089.
dc.identifier.doi10.1007/s00289-024-05183-3
dc.identifier.endpage10952
dc.identifier.issn0170-0839
dc.identifier.issn1436-2449
dc.identifier.issue12
dc.identifier.scopus2-s2.0-85188127216
dc.identifier.scopusqualityQ1
dc.identifier.startpage10933
dc.identifier.urihttps://doi.org/10.1007/s00289-024-05183-3
dc.identifier.urihttps://hdl.handle.net/20.500.12587/25172
dc.identifier.volume81
dc.identifier.wosWOS:001187488300001
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofPolymer Bulletin
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_20241229
dc.subjectMagnetic nanoparticle; Allyl methacrylate; Glycidyl methacrylate; Heavy metal; Wastewater; Adsorption
dc.titleNovel magnetic poly(allyl methacrylate-co-glycidyl methacrylate) Fe3O4 nanoparticles: synthesis and evaluation as adsorbents for heavy metals
dc.typeArticle

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