Chiral phosphine oxide aziridinyl phosphonate as a Lewis base catalyst for enantioselective allylsilane addition to aldehydes

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dc.contributor.authorDogan, Ozdemir
dc.contributor.authorBulut, Adnan
dc.contributor.authorTecimer, M. Ali
dc.date.accessioned2020-06-25T18:12:52Z
dc.date.available2020-06-25T18:12:52Z
dc.date.issued2015
dc.departmentKırıkkale Üniversitesi
dc.description.abstractA series of chiral Lewis bases, phosphine oxide ferrocenyl aziridinyl methanol 1-4, phosphinyl aziridinyl phosphonates 5 and 6, and phosphine oxide aziridinyl phosphonates 7 and 8 were screened for allylsilane additions to aldehydes. Among the Lewis bases, 8 was found to catalyze the reaction by forming the product in up to 94% yield and with 77% ee. (C) 2015 Elsevier Ltd. All rights reserved.en_US
dc.description.sponsorshipScientific and Technical Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [TBAG-110T073]; Middle East Technical University Research FoundationMiddle East Technical Universityen_US
dc.description.sponsorshipWe thank the Scientific and Technical Research Council of Turkey (TUBITAK, Grant No. TBAG-110T073) and the Middle East Technical University Research Foundation for the financial support.en_US
dc.identifier.citationclosedAccessen_US
dc.identifier.doi10.1016/j.tetasy.2015.07.002
dc.identifier.endpage969en_US
dc.identifier.issn0957-4166
dc.identifier.issue17en_US
dc.identifier.scopus2-s2.0-84939570249
dc.identifier.scopusqualityN/A
dc.identifier.startpage966en_US
dc.identifier.urihttps://doi.org/10.1016/j.tetasy.2015.07.002
dc.identifier.urihttps://hdl.handle.net/20.500.12587/6060
dc.identifier.volume26en_US
dc.identifier.wosWOS:000360774600014
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofTetrahedron-Asymmetry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleChiral phosphine oxide aziridinyl phosphonate as a Lewis base catalyst for enantioselective allylsilane addition to aldehydesen_US
dc.typeArticle

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