Influence of ruthenium alkylidene complexes bearing tricyclohexylphosphine or 3-bromopyridine ligand on the properties of fluorine containing polymers

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dc.contributor.authorCetinkaya, Sevil
dc.contributor.authorOzker, Taner
dc.contributor.authorKaya, Pembe Hulya
dc.contributor.authorYasar, Emine
dc.contributor.authorBayram, Rifat
dc.date.accessioned2020-06-25T18:07:07Z
dc.date.available2020-06-25T18:07:07Z
dc.date.issued2013
dc.departmentKırıkkale Üniversitesi
dc.description.abstractThe catalytic performance of ruthenium alkylidene complexes bearing tricyclohexylphosphine or 3-bromopyridine ligand in the ring opening metathesis polymerization (ROMP) of fluorine containing monomers, exo-N-4-fluorophenyl-7-oxanorbornene-5,6-dicarboximide (FPhONDI) and exo-N-4-fluorophenyl-norbornene-5,6-dicarboximide (FPhNDI) was investigated. Pure monomers were subjected to ROMP with RuCl2(PCy3)(2)(CHPh) (I), RuCl2(PCy3)(H(2)IMes)(CHPh) (II), RuCl2(3-Br-py)(2)(PCy3)(CHPh) (III) and RuCl2(3-Br-py)(2)(H(2)IMes)(CHPh) (IV). The polymers were fully characterized using NMR, DSC, SEM and GPC. Catalysts I-IV displayed significant ROMP activity, allowing for the synthesis of the corresponding polymers with polydispersity indices (PDIs) in the range of 1.4-4.0. High molecular weight polymers (Mw up to 4.95 x10(5)) were prepared in yields up to 90 %, depending on the initiator and monomer used.en_US
dc.description.sponsorshipKirikkale University FoundationKirikkale Universityen_US
dc.description.sponsorshipWe thank the Kirikkale University Foundation for the financial support of this work.en_US
dc.identifier.citationclosedAccessen_US
dc.identifier.doi10.1007/s00289-013-0960-x
dc.identifier.endpage2410en_US
dc.identifier.issn0170-0839
dc.identifier.issue8en_US
dc.identifier.scopus2-s2.0-84880846716
dc.identifier.scopusqualityQ1
dc.identifier.startpage2399en_US
dc.identifier.urihttps://doi.org/10.1007/s00289-013-0960-x
dc.identifier.urihttps://hdl.handle.net/20.500.12587/5484
dc.identifier.volume70en_US
dc.identifier.wosWOS:000321921800018
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringeren_US
dc.relation.ispartofPolymer Bulletin
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCatalysten_US
dc.subjectROMPen_US
dc.subjectRuthenium alkylideneen_US
dc.subjectFluorine polymeren_US
dc.subjectProperties and characterizationen_US
dc.titleInfluence of ruthenium alkylidene complexes bearing tricyclohexylphosphine or 3-bromopyridine ligand on the properties of fluorine containing polymersen_US
dc.typeArticle

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