The electronic transport properties of the [Co2(L)L′(dioxane)2(NO3)2](NO3)2 complex

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dc.contributor.authorYakuphanoglu, F.
dc.contributor.authorAydogdu, Y.
dc.contributor.authorGomleksiz, M.
dc.contributor.authorSekerci, M.
dc.contributor.authorAgan, S.
dc.contributor.authorAlkan, C.
dc.date.accessioned2020-06-25T17:35:32Z
dc.date.available2020-06-25T17:35:32Z
dc.date.issued2003
dc.departmentKırıkkale Üniversitesi
dc.description.abstractThe temperature dependence of the electrical conductivity, microstructure and crystal structure properties of the [Co,(L)L'(dioxane)(2)(NO3)(2)](NO3)(2) complex was investigated. The X-ray diffraction showed that the [Co,(L)L'(dioxane)(2) (NO3)(2)](NO3)(2) has a triclinic structure. Temperature dependence of the conductivity curve of the complex exhibited two conduction regions, and while increase of conductivity with temperature in the first region is of hopping conduction which takes place in localized states, the conduction in the second region is of Arrhenius-type. These conduction mechanisms are related to intermolecular and intramolecular conduction progresses. The electrical conductivity of the [Co-2(L)L'(dioxane)(2)(NO3)(2)](NO3)(2) complex was 2.57 x 10(-7) (S/cm) at room temperature with activation energy of 0.46 eV which showed semiconductivity behavior. (C) 2002 Published by Elsevier Science B.V.en_US
dc.identifier.citationclosedAccessen_US
dc.identifier.doi10.1016/S0167-577X(02)01178-3
dc.identifier.endpage2224en_US
dc.identifier.issn0167-577X
dc.identifier.issue15en_US
dc.identifier.scopus2-s2.0-0037383306
dc.identifier.scopusqualityQ1
dc.identifier.startpage2219en_US
dc.identifier.urihttps://doi.org/10.1016/S0167-577X(02)01178-3
dc.identifier.urihttps://hdl.handle.net/20.500.12587/3146
dc.identifier.volume57en_US
dc.identifier.wosWOS:000182126000015
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Bven_US
dc.relation.ispartofMaterials Letters
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectcomplexen_US
dc.subjectsemiconductoren_US
dc.subjectelectrical conductivityen_US
dc.titleThe electronic transport properties of the [Co2(L)L′(dioxane)2(NO3)2](NO3)2 complexen_US
dc.typeArticle

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