Poly[triaquabis-(μ(2)-3-carboxy-pyrazine-2-carboxyl-ato)dilithium(I)]

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dc.contributor.authorTombul, Mustafa
dc.contributor.authorGuven, Kutalmis
dc.contributor.authorBuyukgungor, Orhan
dc.date.accessioned2020-06-25T17:44:50Z
dc.date.available2020-06-25T17:44:50Z
dc.date.issued2008
dc.description.abstractIn the title compound, [Li-2(C6H3N2O4)(2)(H2O)(3)](n), the coordination number for both independent Li+ cations is five. One of the Li+ ions has a distorted trigonal-bipyramidal geometry, coordinated by one of the carboxyl O atoms of a 3-carboxypyrazine-2-carboxylate ligand, two O atoms from two water molecules, and an N and a carboxylate O atom of a second 3-carboxypyrazine-2-carboxylate ligand. The other Li+ ion also has a distorted trigonal-bipyramidal geometry, coordinated by one water molecule and two 3-carboxypyrazine-2-carboxylate ligands through an N and a carboxylate O atom from each. One of the carboxyl groups of the two ligands takes part in an intramolecular O-H center dot center dot center dot O hydrogen bond. The stabilization of the crystal structure is further assisted by O-H center dot center dot center dot O, O-H center dot center dot center dot N and C-H center dot center dot center dot O hydrogen-bonding interactions involving the water molecules and carboxylate O atoms.en_US
dc.identifier.citationTombul, M., Güven, K., & Büyükgüngör, O. (2008). Poly[triaquabis-(μ(2)-3-carboxy-pyrazine-2-carboxyl-ato)dilithium(I)]. Acta crystallographica. Section E, Structure reports online, 64(Pt 3), m491–m492.en_US
dc.identifier.doi10.1107/S1600536808004467
dc.identifier.endpageU557en_US
dc.identifier.issn1600-5368
dc.identifier.pmid21201874
dc.identifier.startpageM491en_US
dc.identifier.urihttps://doi.org10.1107/S1600536808004467
dc.identifier.urihttps://hdl.handle.net/20.500.12587/4208
dc.identifier.volume64en_US
dc.identifier.wosWOS:000253792100042
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherBlackwell Publishingen_US
dc.relation.ispartofActa Crystallographica Section E-Structure Reports Online
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.titlePoly[triaquabis-(μ(2)-3-carboxy-pyrazine-2-carboxyl-ato)dilithium(I)]en_US
dc.typeArticle

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