Synthesis and crystal structure of bis[2-[N-(2-chlorophenyl)formimidayl]-1-naphtholato]-(6Cl)copper(II)

Basit Öğe Kaydı
dc.contributor.authorUnver, H
dc.contributor.authorDurlu, TN
dc.date.accessioned2020-06-25T17:34:46Z
dc.date.available2020-06-25T17:34:46Z
dc.date.issued2001
dc.departmentKırıkkale Üniversitesi
dc.descriptionUnver, Huseyin/0000-0003-3968-4385
dc.description.abstractThe title compound, bis[2-[N-(2-chlorophenyl)formimidayl]-1-naphtholato]-(6Cl) copper(II), [Cu(C(1)7H(1)1NOCl)(2)] (1) was synthesized and its crystal structure was determined. The Compound 1 is monoclinic, space group P2(1)/c with a = 9.146(3) Angstrom, b = 18.724(3) Angstrom, c = 16.230(2) Angstrom, beta = 96.46(1)degrees, V = 2761.8(11) Angstrom(3), Z = 4, D-c = 1.503 g cm(-)3, mu(Mo Kalpha) = 1.020 mm(-)1, R = 0.0606 for 2361 reflections [I > 2sigma(I)]. In the title compound, the Cu atom is coordinated by an N2O2 donor set from the imine-phenol ligand in a slightly distorted square planar coordination geometry, with the two phenolate O atoms being deprotonated. The Cu-O bond lengths are 1.878(4) and 1.889(4) Angstrom, the Cu-N bond lengths are 1.980(5) and 1.985(5) Angstrom. The angles O1-Cu-N1 and O2-Cu-N2 are 90.96(19) and 90.72(19)degrees, respectively.en_US
dc.identifier.citationclosedAccessen_US
dc.identifier.doi10.1023/A:1015611131460
dc.identifier.endpage483en_US
dc.identifier.issn1074-1542
dc.identifier.issue11-12en_US
dc.identifier.scopus2-s2.0-0035541653
dc.identifier.scopusqualityQ3
dc.identifier.startpage479en_US
dc.identifier.urihttps://doi.org/10.1023/A:1015611131460
dc.identifier.urihttps://hdl.handle.net/20.500.12587/2880
dc.identifier.volume31en_US
dc.identifier.wosWOS:000175875000003
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherKluwer Academic/Plenum Publen_US
dc.relation.ispartofJournal Of Chemical Crystallography
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSchiff base complexen_US
dc.subjectcrystal structureen_US
dc.subjectcoordination geometryen_US
dc.subjectH-1 NMRen_US
dc.subjectsquare planaren_US
dc.titleSynthesis and crystal structure of bis[2-[N-(2-chlorophenyl)formimidayl]-1-naphtholato]-(6Cl)copper(II)en_US
dc.typeArticle

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
[ X ]
İsim:
Synthesis and crystal structure of bis[2-[N-(2-chlorophenyl)formimidayl]-1-naphtholato]-(6Cl)copper(II).pdf
Boyut:
48.03 KB
Biçim:
Adobe Portable Document Format
Açıklama:
Tam Metin/Full Text
İndir

Koleksiyon

WOS İndeksli Yayınlar Koleksiyonu
Makale Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu