Efficient synthesis of ferrocenylenones by Friedel-Crafts acylation with EtAlCl2-Me3Al

dc.contributor.authorDoğan, Özdemir
dc.contributor.authorŞenol, Volkan
dc.contributor.authorZeytinci, Serhat
dc.contributor.authorKoyuncu, Hasan
dc.contributor.authorBulut, Adnan
dc.date.accessioned2020-06-25T17:40:48Z
dc.date.available2020-06-25T17:40:48Z
dc.date.issued2005
dc.departmentKırıkkale Üniversitesi
dc.description.abstractEfficient synthesis of ferrocenyl en ones using a Friedel-Crafts acylation reaction is described. Acryloyl, methacryloyl, crotonoyl, cinnamoyl, and beta-methylcrotonoyl chlorides react with ferrocene in the presence of a Lewis acid (EtAlC2 or EtAlCl2-Me3Al) to give the corresponding ferrocenyl en ones (acryloyl, methacryloyl, crotonoyl, cinnamoyl, and methylcrotonoylferrocenes) in good isolated yields. Besides ferrocenylenones, chloroactylferrocene is also synthesised by this method. (C) 2004 Elsevier B.V. All rights reserved.en_US
dc.identifier.citationclosedAccessen_US
dc.identifier.doi10.1016/j.jorganchem.2004.09.055
dc.identifier.endpage434en_US
dc.identifier.issn0022-328X
dc.identifier.issn1872-8561
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-11844263340
dc.identifier.scopusqualityQ2
dc.identifier.startpage430en_US
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2004.09.055
dc.identifier.urihttps://hdl.handle.net/20.500.12587/3554
dc.identifier.volume690en_US
dc.identifier.wosWOS:000226392200024
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Saen_US
dc.relation.ispartofJournal Of Organometallic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectferrocenylenonesen_US
dc.subjectFriedel-Crafts acylationen_US
dc.subjectethylaluminum dichlorideen_US
dc.subjectLewis aciden_US
dc.titleEfficient synthesis of ferrocenylenones by Friedel-Crafts acylation with EtAlCl2-Me3Alen_US
dc.typeArticle

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