Synthesis and Characterization of bis(N,N-Diethylnicotinamide) p-Halogenobenzoate Complexes of Co(II)

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dc.contributor.authorÖztürkkan, Elif F.
dc.contributor.authorKöse, Dursun Ali
dc.contributor.authorNecefoglu, Hacali
dc.contributor.authorUzun, İbrahim
dc.date.accessioned2020-06-25T17:43:36Z
dc.date.available2020-06-25T17:43:36Z
dc.date.issued2007
dc.descriptionOzturkkan, Fureya Elif/0000-0001-6376-4161; Hokelek, Tuncer/0000-0002-8602-4382; Ozturkkan, Fureya Elif/0000-0001-6376-4161; Kose, Dursun Ali/0000-0003-4767-6799; uzun, ibrahim/0000-0001-9725-2009
dc.description.abstractHalogenobenzoates are commonly applied in industrial and medical fields. Four novel mixed ligand complexes of Co(II) with p-florobenzoate, p-chlorobenzoate, p-bromobenzoate, p-iodobenzoate and N,N-diethylnicotinamide were synthesized and characterized on the basis of elemental analysis, FT-IR spectroscopic study, solid state UV-Vis spectrometric and magnetic susceptibility data. The thermal behaviour of the complexes was studied by simultaneous. TG-DTA methods in static air atmosphere and the mass spectra data are recorded. According to the microanlytical results, formulae of complexes are C34H36N4O8FCo, C34H36N4O8ClCo, C34H36N4O8BrCo and C34H36N4O8ICo. The complexes contain two mole of coordination waters, two mole of p-halogenobenzoate and two mole of N,N-diethylnicotinamide (dena) ligands per formula unit. In these complexes, the p-halogenobenzoate and N,N-diethylnicotin-amide behave as monodentate ligand through acidic oxygen and nitrogen of pyridine ring. The decomposition pathways and the stability of the complexes are interpreted in the terms of the structural data. The final decomposition products were found to be the CoO.en_US
dc.identifier.citationclosedAccessen_US
dc.identifier.endpage4888en_US
dc.identifier.issn0970-7077
dc.identifier.issn0975-427X
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-34547913096
dc.identifier.scopusqualityQ4
dc.identifier.startpage4880en_US
dc.identifier.urihttps://hdl.handle.net/20.500.12587/3815
dc.identifier.volume19en_US
dc.identifier.wosWOS:000248368300105
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherAsian Journal Of Chemistryen_US
dc.relation.ispartofAsian Journal Of Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCo(II) complexesen_US
dc.subjectN,N-diethylnicotinamideen_US
dc.subjectp-halogenobenzoateen_US
dc.subjectthermal decompositionen_US
dc.titleSynthesis and Characterization of bis(N,N-Diethylnicotinamide) p-Halogenobenzoate Complexes of Co(II)en_US
dc.typeArticle

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