Synthesis and catalytic evaluation of a ruthenium alkylidene complex bearing methoxy-pyridine ligand

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dc.contributor.authorCetinkaya, Sevil
dc.contributor.authorYasar, Emine
dc.date.accessioned2020-06-25T18:07:06Z
dc.date.available2020-06-25T18:07:06Z
dc.date.issued2013
dc.departmentKırıkkale Üniversitesi
dc.description.abstractModern well-defined ruthenium alkylidene complexes became preferred catalysts for a great variety of metathesis reactions. In this study, an air-stable new ruthenium alkylidene catalyst bearing 3-methoxypyridine has been prepared in one pot at high yields using commercially available [(PCy3)(2)Cl2Ru=CHPh] catalyst. Ruthenium based complex, (PCy3)(3-MeOPy)(2)(Cl)(2)Ru=CHPh, was characterized by a H-1 NMR doublet at 20.00 (J=11.9 Hz) for the Ru=CH proton. The catalyst was tested in model ROMP reactions and found to be very effective for ring-opening metathesis polymerization (ROMP). The optimal conditions for the polymerization of exo-N-benzylnorbornene-5,6-dicarboximide using the newly synthesized catalytic system were determined. (C) 2013 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipKirikkale University Foundation (Turkey)Kirikkale University [2011-08]en_US
dc.description.sponsorshipFinancial support from the Kirikkale University Foundation (Turkey), (Project No. 2011-08) is gratefully acknowledged.en_US
dc.identifier.citationclosedAccessen_US
dc.identifier.doi10.1016/j.apcata.2013.05.030
dc.identifier.endpage141en_US
dc.identifier.issn0926-860X
dc.identifier.scopus2-s2.0-84879232005
dc.identifier.scopusqualityQ1
dc.identifier.startpage136en_US
dc.identifier.urihttps://doi.org/10.1016/j.apcata.2013.05.030
dc.identifier.urihttps://hdl.handle.net/20.500.12587/5474
dc.identifier.volume464en_US
dc.identifier.wosWOS:000323805300017
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Bven_US
dc.relation.ispartofApplied Catalysis A-General
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectRuthenium catalysten_US
dc.subjectROMPen_US
dc.subjectMetathesisen_US
dc.subjectPolynorbornene dicarboximideen_US
dc.subjectHomogeneous catalysten_US
dc.titleSynthesis and catalytic evaluation of a ruthenium alkylidene complex bearing methoxy-pyridine liganden_US
dc.typeArticle

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