Electrochemical polymerization of 4-allyl-1,2-dimethoxybenzene
Yükleniyor...
Tarih
2004
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier Science Bv
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Redox behaviour of 4-allyl-1,2-dimethoxybenzene (DMAB) was studied by using cyclic voltammetry and electro-chemical polymerization was conducted at the measured peak potential. Constant potential electrolysis of the monomer was carried out in acetonitrile-tetrabutylammonium-tetrafluoroborate, solvent-electrolyte couple, at room temperature. Electrochemical polymerization of the monomer yielded insoluble polymer film on the electrode surface together with the low molecular weight polymers in bulk of the solution. The effect of temperature on the rate of electro-chemical polymerization was also studied. The structural analyses of the polymers were done by H-1-NMR and FTIR spectroscopy. Molecular weight of the soluble polymer was determined by cryoscopy. (C) 2004 Elsevier B.V. All rights reserved.
Açıklama
Anahtar Kelimeler
4-allyl-1,2-dimethoxybenzene, cyclic voltammetry, constant potential electrolysis, electrochemical polymerization
Kaynak
Reactive & Functional Polymers
WoS Q Değeri
Q1
Scopus Q Değeri
Q1
Cilt
61
Sayı
2
Künye
closedAccess
