Synthesis, electrochemical and spectroscopic properties of ferrocene-based compounds
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Tarih
2022
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Springer Int Publ Ag
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Ferrocene derivatives have been synthesized by the Suzuki cross-coupling reaction of ferroceneboronic acid with various aryl/heteroaryl halides. The reactions yield ferrocenyl derivatives with overall yields varying between 35 and 98%. The derivatives have been characterized by (HNMR)-H-1, C-13 NMR, IR, HRMS and elemental analysis. The structure-property relationship has been investigated based on UVNis spectroscopy and cyclic voltammetry. Cyclic voltammetry studies revealed when the side group of ferrocenes were an electron-donating, lower oxidation was displayed. On the other hand, the strong electron-withdrawing group had a higher oxidation potential. [GRAPHICS] .
Açıklama
Anahtar Kelimeler
Ferrocene derivatives; Palladium catalyst; Cross-coupling; UV-vis spectroscopy; Cyclic voltammetry
Kaynak
Chemical Papers
WoS Q Değeri
Q3
Scopus Q Değeri
Q2
Cilt
76
Sayı
4
