Synthesis, electrochemical and spectroscopic properties of ferrocene-based compounds

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dc.authoridOsken, Ipek/0000-0002-9109-7789
dc.authoridTaskor Onel, Gulce/0000-0002-9375-2329
dc.authorid, EMINE/0000-0001-5685-1742
dc.contributor.authorOnel, Gulce Taskor
dc.contributor.authorKaraaslan, Emine Ozgul
dc.contributor.authorOsken, Ipek
dc.contributor.authorSaygili, Nezire
dc.date.accessioned2025-01-21T16:44:49Z
dc.date.available2025-01-21T16:44:49Z
dc.date.issued2022
dc.departmentKırıkkale Üniversitesi
dc.description.abstractFerrocene derivatives have been synthesized by the Suzuki cross-coupling reaction of ferroceneboronic acid with various aryl/heteroaryl halides. The reactions yield ferrocenyl derivatives with overall yields varying between 35 and 98%. The derivatives have been characterized by (HNMR)-H-1, C-13 NMR, IR, HRMS and elemental analysis. The structure-property relationship has been investigated based on UVNis spectroscopy and cyclic voltammetry. Cyclic voltammetry studies revealed when the side group of ferrocenes were an electron-donating, lower oxidation was displayed. On the other hand, the strong electron-withdrawing group had a higher oxidation potential. [GRAPHICS] .
dc.description.sponsorshipHacettepe University [BAP-2013, 013 D09 301 002]
dc.description.sponsorshipThis research was supported by Hacettepe University (BAP-2013, 013 D09 301 002).
dc.identifier.doi10.1007/s11696-021-02034-7
dc.identifier.endpage2257
dc.identifier.issn0366-6352
dc.identifier.issn2585-7290
dc.identifier.issue4
dc.identifier.scopus2-s2.0-85123821354
dc.identifier.scopusqualityQ2
dc.identifier.startpage2249
dc.identifier.urihttps://doi.org/10.1007/s11696-021-02034-7
dc.identifier.urihttps://hdl.handle.net/20.500.12587/25521
dc.identifier.volume76
dc.identifier.wosWOS:000754649900004
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer Int Publ Ag
dc.relation.ispartofChemical Papers
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241229
dc.subjectFerrocene derivatives; Palladium catalyst; Cross-coupling; UV-vis spectroscopy; Cyclic voltammetry
dc.titleSynthesis, electrochemical and spectroscopic properties of ferrocene-based compounds
dc.typeArticle

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