Poly[μ-aqua-di­aqua­(μ2-pyrazine-2,3-di­carboxyl­ato)dilithium(I)]

Tombul, Mustafa; Guven, Kutalmis

Poly[μ-aqua-diaqua(μ2-pyrazine-2,3-dicarboxylato)dilithium(I)]

dc.contributor.author	Tombul, Mustafa
dc.contributor.author	Guven, Kutalmis
dc.date.accessioned	2020-06-25T17:48:07Z
dc.date.available	2020-06-25T17:48:07Z
dc.date.issued	2009
dc.department	Kırıkkale Üniversitesi
dc.description.abstract	The asymmetric unit of the title compound, [Li-2(C6H2N2O4)(H2O)(3)](n), consists of two independent Li+ cations, one pyrazine-2,3-dicarboxylate dianion and three water molecules. One of the Li+ cations has a distorted tetrahedral geometry, coordinated by one of the carboxylate O atoms of the pyrazine-2,3-dicarboxylate ligand and three O atoms from three water molecules, whereas the other Li+ cation has a distorted trigonal-bipyramidal geometry, coordinated by a carboxylate O atom of a symmetry-related pyrazine-2,3-dicarboxylate ligand, two water molecules and a chelating pyrazine-2,3-dicarboxylate ligand (by utilizing both N and O atoms) of an adjacent molecule. The synthesis of a hydrated polymeric dinuclear lithium complex formed with two pyrazine-2,3-dicarboxylic acid ligands has been reported previously [Tombul et al. (2008a). Acta Cryst. E64, m491-m492]. By comparision to the complex reported here, the dinuclear complex formed with two pyrazine-2,3-dicarboxylic acid ligands differs in the coordination geometry of both Li atoms. The crystal structure further features O-H center dot center dot center dot O and O-H center dot center dot center dot N hydrogen-bonding interactions involving the water molecules and carboxylate O atoms.	en_US
dc.description.sponsorship	Kirikkale University Scientific Research Centre, (BAP-Kirikkale), TurkeyKirikkale University	en_US
dc.description.sponsorship	The authors are grateful to Kirikkale University Scientific Research Centre, (BAP-Kirikkale), Turkey, for their generous support.	en_US
dc.identifier.citation	Tombul, M., & Guven, K. (2009). Poly[μ-aqua-diaqua-(μ(2)-pyrazine-2,3-dicarboxyl-ato)dilithium(I)]. Acta crystallographica. Section E, Structure reports online, 65(Pt 12), m1704–m1705.	en_US
dc.identifier.doi	10.1107/S1600536809050570
dc.identifier.endpage	U1732	en_US
dc.identifier.issn	1600-5368
dc.identifier.pmid	21578706
dc.identifier.scopus	2-s2.0-72049114965
dc.identifier.scopusquality	N/A
dc.identifier.startpage	M1704	en_US
dc.identifier.uri	https://doi.org/10.1107/S1600536809050570
dc.identifier.uri	https://hdl.handle.net/20.500.12587/4316
dc.identifier.volume	65	en_US
dc.identifier.wos	WOS:000272244600167
dc.identifier.wosquality	Q4
dc.indekslendigikaynak	Web of Science
dc.indekslendigikaynak	Scopus
dc.indekslendigikaynak	PubMed
dc.language.iso	en
dc.publisher	Wiley-Blackwell	en_US
dc.relation.ispartof	Acta Crystallographica Section E-Structure Reports Online
dc.relation.publicationcategory	Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı	en_US
dc.rights	info:eu-repo/semantics/openAccess	en_US
dc.title	Poly[μ-aqua-diaqua(μ2-pyrazine-2,3-dicarboxylato)dilithium(I)]	en_US
dc.type	Article