New zinc(II)-based catalyst for asymmetric azomethine ylide cycloaddition reactions
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Date
2006
Journal Title
Journal ISSN
Volume Title
Publisher
Amer Chemical Soc
Access Rights
info:eu-repo/semantics/closedAccess
Abstract
A new chiral aziridino alcohol ligand for zinc(II)-catalyzed azomethine ylide cycloadditions is described. In the presence of this catalyst, N-arylidene glycine methyl esters react with a variety of dipolarophiles to give substituted pyrrolidines in very good to excellent chemical yields and up to 95% ee. The absolute sense of asymmetric induction appears to be dipolarophile-dependent.
Description
Garner, Philip/0000-0002-6503-9550
Keywords
Journal or Series
Organic Letters
WoS Q Value
Q1
Scopus Q Value
Q1
Volume
8
Issue
21
Citation
closedAccess
