An alkoxide cluster with 18 Li+ ions encapsulating two borate anions, [(tBuO)12Li18(BO3)2]

Basit Öğe Kaydı
dc.contributor.authorTombul, M.
dc.contributor.authorErrington, R.J.
dc.contributor.authorCoxall, R.A.
dc.contributor.authorClegg, W.
dc.date.accessioned2020-06-25T17:35:27Z
dc.date.available2020-06-25T17:35:27Z
dc.date.issued2003
dc.departmentKırıkkale Üniversitesi
dc.descriptionErrington, John/0000-0001-5696-0332; Clegg, William/0000-0003-1643-5298
dc.description.abstractThe title compound, bis(borato) dodeca(tert-butoxo)octadeca-lithium, [Li-18(BO3)(2)(C4H9O)(12)], is formulated conveniently as [{((BuOLi)-Bu-t)(3)(Li3BO3)}(2)((BuOLi)-Bu-t)(6)]. A central 12-membered ring and two outer six-membered rings are formed by alternating Li+ cations and alkoxide O atoms. Sandwiched between the central ring and each of the outer rings is a planar array of three further Li+ cations surrounding a [BO3](3-) anion. Thus, the molecule consists of a cationic [Li-18((OBu)-Bu-t)(12)](6+) cage encapsulating two borate anions. This compound is the first example of a structurally characterized polynuclear lithium borate, and a rare case of a lithium alkoxide cage with nuclearity greater than eight. All the alkoxide ligands are triply bridging, and the lithium ions have trigonal-planar, trigonal-pyramidal and fourfold coordination, all with major distortions from regular coordination geometry.en_US
dc.identifier.citationclosedAccessen_US
dc.identifier.doi10.1107/S0108270103009636
dc.identifier.endpageM233en_US
dc.identifier.issn0108-2701
dc.identifier.pmid12794331
dc.identifier.scopus2-s2.0-0038234815
dc.identifier.scopusqualityN/A
dc.identifier.startpageM231en_US
dc.identifier.urihttps://doi.org/10.1107/S0108270103009636
dc.identifier.urihttps://hdl.handle.net/20.500.12587/3124
dc.identifier.volume59en_US
dc.identifier.wosWOS:000183345100017
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherBlackwell Munksgaarden_US
dc.relation.ispartofActa Crystallographica Section C-Crystal Structure Communications
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleAn alkoxide cluster with 18 Li+ ions encapsulating two borate anions, [(tBuO)12Li18(BO3)2]en_US
dc.typeArticle

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
[ X ]
İsim:
An alkoxide cluster with 18 Li+ ions encapsulating two borate anions, [(tBuO)12Li18(BO3)2].pdf
Boyut:
219.65 KB
Biçim:
Adobe Portable Document Format
Açıklama:
Tam Metin/Full Text
İndir

Koleksiyon

WOS İndeksli Yayınlar Koleksiyonu
Makale Koleksiyonu
PubMed İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu