Kinetic study of ligand exchange reaction of anions as ligands on DAE-sporopollenin

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dc.contributor.authorErsoz, M
dc.contributor.authorVural, US
dc.contributor.authorYigitoglu, M
dc.contributor.authorSezgin, M
dc.date.accessioned2020-06-25T17:34:33Z
dc.date.available2020-06-25T17:34:33Z
dc.date.issued1996
dc.departmentKırıkkale Üniversitesi
dc.descriptionErsoz, Mustafa/0000-0002-9409-9157; VURAL, UFUK SANCAR/0000-0002-8510-9616
dc.description.abstractThe specific rate coefficients and ligand sorption isotherms of Br and I- as ligands on diaminoethyl-sporopollenin were determined as a function of pH and temperature between 20 and 60 degrees C. The ligand exchange rates were measured just after the rapid mixing of the ligand solution with the resin suspension. The data have also been analyzed to obtain activation parameters Delta G, Delta H, and Delta S for reaction in the corresponding mixture. A single ligand-exchange process was observed; the sorption of ligand increased with decreasing pH and hydrated radius of ligands and increasing temperature. A reaction mechanism which describe the ligand exchange reaction is proposed. (C) 1996 Academic Press, Inc.en_US
dc.identifier.citationclosedAccessen_US
dc.identifier.doi10.1006/jcis.1996.0624
dc.identifier.endpage324en_US
dc.identifier.issn0021-9797
dc.identifier.issue1en_US
dc.identifier.pmid8954670
dc.identifier.scopus2-s2.0-0030560707
dc.identifier.scopusqualityQ1
dc.identifier.startpage319en_US
dc.identifier.urihttps://doi.org/10.1006/jcis.1996.0624
dc.identifier.urihttps://hdl.handle.net/20.500.12587/2766
dc.identifier.volume184en_US
dc.identifier.wosWOS:A1996VV34100034
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherAcademic Press Inc Jnl-Comp Subscriptionsen_US
dc.relation.ispartofJournal Of Colloid And Interface Science
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleKinetic study of ligand exchange reaction of anions as ligands on DAE-sporopolleninen_US
dc.typeArticle

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