Electrochemical polymerization of 2-aminothiazole
Yükleniyor...
Tarih
2011
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Springer
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Electrochemical polymerization of 2-aminothiazole (AT) was studied in acetonitrile with tetrabutylammonium tetrafluoroborate (TBAFB) as the supporting electrolyte via constant potential electrolysis (CPE). The redox behavior of AT was investigated in the same solvent-electrolyte couple by cyclic voltammetry, CV. CPE of AT produced a soluble conducting polymer on the electrode surface. The effects of temperature, monomer concentration and polymerization time on the rate of electrochemical polymerization were also studied. The structural analyses of the polymer were carried out by H-1-NMR, FTIR and UV-VIS spectroscopies and elemental analysis. Thermal properties were studied by DSC and TGA. Conductivity measurements were carried out by four-probe technique and the number average molecular weight, M (n), of the polymer was determined by cryoscopy.
Açıklama
Anahtar Kelimeler
Conducting polymer, Cyclic voltammetry, Electrochemical polymerization, Poly(2-aminothiazole)
Kaynak
Polymer Bulletin
WoS Q Değeri
Q2
Scopus Q Değeri
Q1
Cilt
66
Sayı
6
Künye
closedAccess
