Electrochemical polymerization of 2-aminothiazole

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dc.contributor.authorCiftci, Hakan
dc.contributor.authorTestereci, Hasan Nur
dc.contributor.authorOktem, Zeki
dc.date.accessioned2020-06-25T17:51:56Z
dc.date.available2020-06-25T17:51:56Z
dc.date.issued2011
dc.departmentKırıkkale Üniversitesi
dc.description.abstractElectrochemical polymerization of 2-aminothiazole (AT) was studied in acetonitrile with tetrabutylammonium tetrafluoroborate (TBAFB) as the supporting electrolyte via constant potential electrolysis (CPE). The redox behavior of AT was investigated in the same solvent-electrolyte couple by cyclic voltammetry, CV. CPE of AT produced a soluble conducting polymer on the electrode surface. The effects of temperature, monomer concentration and polymerization time on the rate of electrochemical polymerization were also studied. The structural analyses of the polymer were carried out by H-1-NMR, FTIR and UV-VIS spectroscopies and elemental analysis. Thermal properties were studied by DSC and TGA. Conductivity measurements were carried out by four-probe technique and the number average molecular weight, M (n), of the polymer was determined by cryoscopy.en_US
dc.description.sponsorshipKirikkale UniversityKirikkale University [BAP-2006/13]en_US
dc.description.sponsorshipThe authors are grateful to Kirikkale University Research Fund, BAP-2006/13, for support of this work.en_US
dc.identifier.citationclosedAccessen_US
dc.identifier.doi10.1007/s00289-010-0307-9
dc.identifier.endpage760en_US
dc.identifier.issn0170-0839
dc.identifier.issn1436-2449
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-79551548763
dc.identifier.scopusqualityQ1
dc.identifier.startpage747en_US
dc.identifier.urihttps://doi.org/10.1007/s00289-010-0307-9
dc.identifier.urihttps://hdl.handle.net/20.500.12587/5032
dc.identifier.volume66en_US
dc.identifier.wosWOS:000288174500003
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringeren_US
dc.relation.ispartofPolymer Bulletin
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectConducting polymeren_US
dc.subjectCyclic voltammetryen_US
dc.subjectElectrochemical polymerizationen_US
dc.subjectPoly(2-aminothiazole)en_US
dc.titleElectrochemical polymerization of 2-aminothiazoleen_US
dc.typeArticle

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